Stainless Steel: 304, 316 and 316L
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The difference is molybdenum and carbon. It is invisible, so it has to be proven on paper.
What is in them
All 300 series stainless contains high percentages of nickel and chromium. Nickel stabilizes the austenitic structure. Chromium protects the iron from oxidation, adds heat resistance and forms an invisible chromium-rich film that re-forms itself in the presence of oxygen. That film is what allows steam cleaning and fast sterilization without any coating.
| Grade | What sets it apart | What it buys you |
|---|---|---|
| 304 | The baseline 18/8 chromium nickel grade | Excellent general corrosion resistance, the standard for process equipment |
| 316 | Adds 2 to 3 percent molybdenum | Resistance to chlorides, brines, sulfuric acid, iodides and fatty acids, and more heat resistance |
| 316L | 316 with low carbon, under 0.03 percent | Less carbide formation at welds, so better corrosion resistance in the heat affected zone |
Compatibility with extraction solvents
| Solvent | 304 | 316 / 316L |
|---|---|---|
| Butane, propane | A | A |
| Heptane, hexane | A | A |
| Ethanol, methanol | A | A |
| CO2 | A | A |
| Isopropyl alcohol | B | B |
| Pentane | B | B |
| Acetone | A | A |
A: excellent. B: good, minor effect. Room temperature ratings, with the more conservative value printed where published charts disagree. In practice 304 and 316 are used with IPA and pentane across the industry. Full matrix in REF-CM-01 Chemical Compatibility.
The gaskets matter as much as the steel
- Buna-N and Viton are compatible with butane, propane and heptane at room temperature.
- On any joint that sees chiller or LCO2 temperatures, use PTFE. Hydrocarbon recovery runs to -65°C (-85°F), below the rating of Buna-N and Viton.
- Clean gaskets with isopropyl alcohol. Never use acetone on Buna-N or Viton: acetone attacks both.
Sources. N.B. Oler Tech Tuesday, Stainless Steel: 304, 316 and 316L (2020). Thomas and Betts, 304 Stainless Steel Corrosion Compatibility Chart; Graco, Chemical Compatibility Guide (2013); Industrial Specialties Mfg., 316L Stainless Steel Compatibility Chart (2020). Ratings updated to N.B. Oler REF-CM-01, Rev. 2026.1.